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The reaction of 4-(dimethyl­amino)­pyridine, picolinic acid and stannic chloride yields the title monosolvated salt, (C 13 H 10 NO)[SnCl 4 (C 6 H 4 NO 2 )]·CH 3 OH. The Sn IV  atom is  N , O -chelated by the picolinate ion in a  cis -SnNOCl 4  octa­hedral geometry. The cation is linked to the methanol solvent mol­ecule by an O—H⋯O hydrogen bond; the solvent mol­ecule itself is a hydrogen-bond donor to the uncoordinating carboxyl­ate O atom of the anion. The cations and anions are linked by weak N—H⋯Cl inter­actions, forming a chain running along the  b  axis.

10-Hydroxybenzo[h]quinolin-1-ium tetrachlorido(pyridine-2-carboxylato-κ2 N,O)stannate(IV) methanol monosolvate

10-Hydroxybenzo[h]quinolin-1-ium tetrachlorido(pyridine-2-carboxylato-κ² N,O)stannate(IV) methanol monosolvate