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The 1,10-phenanthroline-chelated Zn atom in the polymeric title compound, {[Zn(C 7 H 4 O 6 S)(C 12 H 8 N 2 )(H 2 O) 2 ]·1.5H 2 O}  n  , is connected to the sulfonate O atom of one 4-hy­droxy-3-sulfonato­benzoate dianion and to the carboxyl­ate O atom of another dianion. It is also coordinated by two water mol­ecules in an overall octa­hedral environment. The dianion links adjacent metal atoms into a chain running along [110]. The chains are linked by O—H⋯O hydrogen bonds into a three-dimensional network.

acta crystallographica. section e

catena-Poly[[[diaqua(1,10-phenanthroline-κ2 N,N′)zinc]-μ-4-hydroxy-3-sulfonatobenzoato-κ2 O 3:O 1] sesquihydrate]