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In the title compound, C 22 H 16 O 4 , the 7-phenyl ring is inclined at dihedral angles of 36.73 (9) and 69.37 (9)° with respect to the biphenyl benzene rings. The two benzene rings of the biphenyl unit form a dihedral angle of 55.99 (8)°. There are no significant hydrogen bonds observed in the crystal of this compound.

1-Phenylethane-1,2-diyl 1,1′-biphenyl-2,2′-dicarboxylate