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In the title hydrated mol­ecular salt, (C 7 H 7 N 2 S) 2 [Zn(C 8 H 8 O 5 ) 2 ]·6H 2 O, which is isotypic with its Mn II , Co II  and Ni II  analogues, the Zn 2+  ion lies on a crystallographic inversion centre and a distorted ZnO 6  octa­hedral coordination geometry arises from the two doubly deprotonated  O , O ′, O ′′-tridentate ligands. In the crystal, the components are linked by N—H⋯O a , N—H⋯O w , O w —H⋯O a  and O w —H⋯O w  hydrogen bonds (w = water and a = anion).

acta crystallographica. section e

Bis(2-aminobenzothiazol-3-ium) bis(7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylato-κ3O2,O3,O7)zincate hexahydrate