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In the title compound, [Cu(C 12 H 18 N 2 O 2 )]·0.25H 2 O, the coordination of the  O , N , N ′, O ′-tetra­dentate ligand results in a  cis -CuN 2 O 2  square-planar geometry for the metal ion and the presence of two six-membered and one five-membered chelate rings. The complete complex mol­ecule is close to planar (r.m.s. deviation = 0.047 Å). The uncoordinated water mol­ecule (O-atom site symmetry 2) was modelled as half occupied. In the crystal, C—H⋯O w  and O w —H⋯O (w = water) hydrogen bonds link the components into layers parallel to  ab  plane.

[4,4′-(Ethane-1,2-diyldinitrilo)bis(pent-2-en-2-olato)]copper(II) 0.25-hydrate