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In the three-dimensional tetra-chloro-phthalate-bridged title complex [Er(C(8)Cl(4)O(4))(H(2)O)(7)](C(8)HCl(4)O(4))·C(8)H(2)Cl(4)O(4)·H(2)O, the Er(III) ion is coordinated in form of a distorted square antiprism by an O atom of a tetra-chloro-phthalate ligand and by seven water O atoms. Extensive hydrogen bonds establish a layered network structure extending parallel to (001).

acta crystallographica. section e

Heptaaqua(3,4,5,6-tetrachlorophthalato-κ<i>O</i><sup>1</sup>)erbium(III) 2-carboxy-3,4,5,6-tetrachlorobenzoate–3,4,5,6-tetrachlorophthalic acid–water (1/1/1)

Heptaaqua(3,4,5,6-tetrachlorophthalato-κO1)erbium(III) 2-carboxy-3,4,5,6-tetrachlorobenzoate–3,4,5,6-tetrachlorophthalic acid–water (1/1/1)

Heptaaqua(3,4,5,6-tetrachlorophthalato-κO¹)erbium(III) 2-carboxy-3,4,5,6-tetrachlorobenzoate–3,4,5,6-tetrachlorophthalic acid–water (1/1/1)