English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

The asymmtric unit of the title compound, (C 27 H 50 N)[Ni(C 3 S 5 ) 2 ], contains two  N -benzyl- N , N -dimethyl­octa­decan-1-aminium cations, [BDA] + , and two [Ni(dmit) 2 ] −  anions (dmit = 2-thioxo-1,3-dithiole-4,5-dithiol­ate). The C 18  chains in both cations adopt almost ideal extended conformations. The Ni III  atoms are coordinated by two  S , S ′-bidentate ligands, generating NiS 4  square planes. Short Ni⋯S [3.734 (2) Å] and S⋯S contacts [3.5438 (15) Å] occur in the crystal structure; if these are considered to be bonding inter­actions, then infinite sheets of anions parallel to (111) arise.

acta crystallographica. section e

N-Benzyl-N,N-dimethyloctadecan-1-aminium (2-thioxo-1,3-dithiole-4,5-dithiolato-κ2S4,S5)nickelate(III)