English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

In the title salt co-crystal, [Ag(C(6)H(5)N(2)O)(C(6)H(6)N(2)O)]ClO(4)·[Ag(C(6)H(6)N(2)O)(2)], the asymmetric unit comprises a [Ag(LH)(2)](+) cation, a perchlorate anion and a neutral (LH)AgL mol-ecule, where LH is pyridine-2-carboxaldoxime. Both silver-containing species feature N,N'-chelating LH and L ligands, which define an N(4) donor set that is highly distorted [dihedral angles between AgC(2)N(2) chelate rings = 45.7 (3) and 44.3 (2)°, respectively] owing, in part, to the close approach of a neighbouring Ag atom, leading to an argentophilic inter-action [Ag⋯Ag = 3.1868 (11) Å]. The mol-ecular conformations are stabilized by intra-molecular O-H⋯O hydrogen bonds. In the crystal, O-H⋯O inter-actions lead to supra-molecular chains along [010]. Chains aggregate into layers in the ab plane, defining channels along [100] in which reside the perchlorate anions; the latter are disordered over two overlapped orientations in a 50:50 ratio.

acta crystallographica. section e

[(E)-Oxido(pyridin-2-ylmethylidene)amine-κ2N,N′][(E)-N-(pyridin-2-ylmethylidene)hydroxylamine-κ2N,N′]silver(I) perchlorate–bis[(E)-N-(pyridin-2-ylmethylidene)hydroxylamine-κ2N,N′]silver(I) (1/1)