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In the title salt, C 5 H 7 Br 2 N 2   + ·Br − , the cation and anion are connected by an N—H⋯Br hydrogen bond. In the crystal, there are inter­calated layers parallel to (10-2) in which bromide ions are located between the cations. Weak inter­molecular C—H⋯Br hydrogen bonds are also observed.

4,5-Dibromo-1,2-dimethyl-1H-imidazol-3-ium bromide