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The mononuclear title compound, [Ti(C(11)H(8)ClN(2))(2)(C(2)H(6)N)(2)]·C(7)H(8), was synthesized by the reaction of N-(4-chloro-phen-yl)-2-pyrrolylcarbaldimine with Ti(C(2)H(6)N)(4). The Ti(IV) ion is situated on a twofold rotation axis and displays a distorted octa-hedral geometry defined by four N atoms from two 2-[(4-chloro-phen-yl)imino-meth-yl]pyrrol-1-ide ligands and two N atoms from two dimethyl-amine ligands. The Ti-N(pyrrole) bond length [2.1041 (19) Å] is longer than the Ti-N(dimethyl-amine) bond length [1.9013 (19) Å]; the imine N atom exhibits the longest Ti-N bond [2.3152 (17) Å]. The toluene solvent mol-ecule is located on a twofold rotation axis running through the C atom of the methyl group. Consequently, the H atoms of the latter are rotationally disordered. The compound contains no markable hydrogen-bonding inter-actions.

Bis{2-[(4-chlorophenyl)iminomethyl]pyrrol-1-ido-κ2N,N′}bis(dimethylamido-κN)titanium(IV) toluene monosolvate

Bis{2-[(4-chlorophenyl)iminomethyl]pyrrol-1-ido-κ²N,N′}bis(dimethylamido-κN)titanium(IV) toluene monosolvate