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The Co II  ion in the title mononuclear compound, [Co(C 11 H 7 N 6 ) 2 (H 2 O) 2 ]·2CH 3 OH, is located on an inversion center and is six-coordinated in a distorted octa­hedral geometry defined by four N atoms from two deprotonated 5-(pyrazin-2-yl-κ N )-3-(pyridin-4-yl)-1 H -1,2,4-triazol-1-ide (ppt) ligands and two water mol­ecules. In the crystal, the complex mol­ecules and lattice methanol mol­ecules are linked  via  O—H⋯N and O—H⋯O hydrogen bonds, generating a two-dimensional supra­molecular network parallel to (001). π–π inter­actions between the triazole and pyrazine rings and between the pyridine rings are present [centroid–centroid distances = 3.686 (3) and 3.929 (4) Å, respectively].

Diaquabis[5-(pyrazin-2-yl-κN1)-3-(pyridin-4-yl)-1H-1,2,4-triazol-1-ido-κN1]cobalt(II) methanol disolvate

Diaquabis[5-(pyrazin-2-yl-κN¹)-3-(pyridin-4-yl)-1H-1,2,4-triazol-1-ido-κN¹]cobalt(II) methanol disolvate