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The mononuclear title complex, [Ti(C 2 H 6 N) 2 (C 12 H 11 N 2 ) 2 ], was synthesized by the reaction of 1-phenyl- N -[(pyrrol-2-yl)methyl­idene]methanamine with Ti(NMe 2 ) 4 . The Ti IV  atom is coordinated in a distorted octa­hedral geometry by four N atoms from two derivatized methanamine ligands and two N atoms from two dimethyl­amide ions. The dihedral angles between the pyrrole and phenyl rings in the bidentate ligands are 62.36 (9) and 78.32 (8)°. In the crystal, a weak π–π stacking inter­action [centroid–centroid distance = 3.864 (2) Å] involving centrosymmetrically related mol­ecules is observed.

Bis[2-(benzyliminomethyl)pyrrol-1-ido-κ2N,N′]bis(dimethylamido-κN)titanium(IV)

Bis[2-(benzyliminomethyl)pyrrol-1-ido-κ²N,N′]bis(dimethylamido-κN)titanium(IV)