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In the title compound, [ZnCl 2 (C 20 H 18 N 4 )]  n  , the Zn II  ion lies on a twofold rotation axis and is four-coordinated in a tetra­hedral geometry defined by two Cl anions and two N atoms from two 4,4′-bis­[(imidazol-1-yl)meth­yl]biphenyl ligands. The mid-point of the ligand is located on an inversion center, and shows a  trans  conformation. The ligands link the Zn II  ions, forming a chain structure along [10-1].

catena-Poly[(dichloridozinc)-μ-4,4′-bis[(1H-imidazol-1-yl)methyl]biphenyl-κ2N3:N3′]

catena-Poly[(dichloridozinc)-μ-4,4′-bis[(1H-imidazol-1-yl)methyl]biphenyl-κ²N³:N^3′]