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In the title dinuclear complex, [Cu 2 (C 5 H 6 BrN 2 )Cl 3 (C 5 H 7 BrN 2 ) 4 ]·CH 3 CN, both Cu II  ions are in slightly distorted square-pyramidal coordination geometries. The basal planes are defined by three N atoms from three 4-bromo-3,5-dimethyl­pyrazolate ligands, one of which is bridging, and one Cl ligand. A bridging Cl ligand forms the apical site for both Cu II  ions. In the crystal, N—H⋯Cl hydrogen bonds connect complex mol­ecules into chains along [100]. Intra­molecular N—H⋯Cl hydrogen bonds are also observed.

acta crystallographica. section e

(μ-4-Bromo-3,5-dimethylpyrazolato-κ2N1:N2)-μ-chlorido-bis[bis(4-bromo-3,5-dimethylpyrazole-κN2)chloridocopper(II)] acetonitrile monosolvate