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In the cation of the title compound, C 23 H 25 N 4 O + ·PF 6   − , the imidazolium ring make dihedral angles of 87.20 (6) and 79.89 (5)° with the pyridine ring and the quinoline system, respectively. In the crystal, C—H⋯F and C—H⋯N hydrogen bonds are observed.

3-[(8-Butoxyquinolin-2-yl)methyl]-1-(pyridin-2-ylmethyl)-1H-imidazol-3-ium hexafluoridophosphate