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In the title compound, {[Ce(C 14 H 9 N 2 O 5 )(C 14 H 8 N 2 O 5 )(H 2 O) 2 ]·H 2 O}  n  , three carboxyl groups of two independent isophthalate anions are deprotonated and they bridge the Ce III  cations, forming a two-dimensional polymeric structure parallel to (001); another carboxyl group is not deprotonated and links with the adjacent pyridine ring  via  an O—H⋯N hydrogen bond. The Ce III  cation is coordinated by six O atoms from carboxyl groups and two O atoms from coordinated water mol­ecules in a distorted square-anti­prismatic arrangement. Extensive O—H⋯O and O—H⋯N hydrogen bonding occurs in the crystal structure.

acta crystallographica. section e

Poly[[diaqua[μ<sub>2</sub>-3-carboxy-5-(pyridine-4-carboxamido)benzoato][μ<sub>4</sub>-5-(pyridine-4-carboxamido)isophthalato]cerium(III)] monohydrate]

Poly[[diaqua[μ2-3-carboxy-5-(pyridine-4-carboxamido)benzoato][μ4-5-(pyridine-4-carboxamido)isophthalato]cerium(III)] monohydrate]

Poly[[diaqua[μ₂-3-carboxy-5-(pyridine-4-carboxamido)benzoato][μ₄-5-(pyridine-4-carboxamido)isophthalato]cerium(III)] monohydrate]