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In the title compound, [HgCl 2 (C 6 H 5 NO 2 ) 2 ]  n  , the Hg II  cation is located on an inversion center and is six-coordinated in a distorted octa­hedral geometry by two N atoms from two pyridine-3-carb­oxy­lic acid mol­ecules and four bridging Cl −  anions. The bridging function of the Cl −  anions leads to polymeric chains running along the  a  axis. One Hg—Cl bond is much longer than the other. In the crystal, O—H⋯O and weak C—H⋯Cl hydrogen bonds are observed.

catena-Poly[[bis(pyridine-3-carboxylic acid-κN)mercury(II)]-di-μ-chlorido]