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In the title complex, [Zn(C 10 H 8 N 5 )Cl]  n  , the Zn II  ion is four-coordinated by one Cl atom and three N atoms from two  in situ -generated deprotonated 5-(1-methyl-1 H -benzimidazol-2-yl-κ N   3 )-1,2,3-triazol-1-ide ligands in a slightly distorted tetra­hedral geometry. The Zn II  ions are bridged by the ligands, forming a helical chain along [001]. C—H⋯N and C—H⋯Cl hydrogen bonds and π–π inter­actions between the imidazole rings [centroid–centroid distance = 3.4244 (10) Å] assemble the chains into a three-dimensional supra­molecular network.

acta crystallographica. section e

catena-Poly[(chloridozinc)-μ-5-(1-methyl-1H-benzimidazol-2-yl-κN3)-1,2,3-triazol-1-ido-κ2N1:N3]