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The asymmetric unit of the title solvate, C 20 H 14 O 4 ·2C 2 D 6 OS, contains half of the substituted terephthalic acid mol­ecule and one solvent mol­ecule. The centroid of the central benzene ring in the acid mol­ecule is coincident with a crystallographic inversion center. Neither the carboxyl nor the phenyl substituents are coplanar with the central aromatic ring, showing dihedral angles of 53.18 (11) and 47.83 (11)°, respectively. The dimethyl sulfoxide solvent mol­ecules are hydrogen bonded to the carb­oxy­lic acid groups.

1,1′:4′,1′′-Terphenyl-2′,5′-dicarboxylic acid dimethyl sulfoxide-d6disolvate

1,1′:4′,1′′-Terphenyl-2′,5′-dicarboxylic acid dimethyl sulfoxide-d₆disolvate