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In the title compound, [Rh(C 5 H 7 O 2 )(C 18 H 14 BrP)(CO)], the Rh I  atom adopts a slightly distorted square-planar geometry involving two O atoms [Rh—O = 2.077 (2) and 2.033 (2) Å] of the acetyl­acetonate ligand, one carbonyl C atom [Rh—C = 1.813 (2) Å] and one P atom [Rh—P = 2.242 (5) Å] of the PPh 2 (2-BrC 6 H 4 ) phosphane ligand. Difference electron density maps indicate a disorder of the Br atom over two positions in an approximate 0.95:0.05 ratio. However, this disorder could not be resolved satisfactorily with the present data.

(Acetylacetonato-κ2O,O′)[(2-bromophenyl)diphenylphosphane-κP]carbonylrhodium(I)

(Acetylacetonato-κ²O,O′)[(2-bromophenyl)diphenylphosphane-κP]carbonylrhodium(I)