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The asymmetric unit of the title compound, C 8 H 6 F 3 N 2   + ·BF 4   − ·C 8 H 5 F 3 N 2 ·H 2 O, consists of two 2-trifluoro­methyl­benzimidazole mol­ecules, each of which is protonated on a 50% basis, one tetra­fluoro­borate anion and a water mol­ecule. The two 2-trifluoromethylbenzimidazole mol­ecules thus exist as half-neutral half-cation entities. They are linked by N—H⋯N hydrogen bonds involving the half-occupancy hydrogens in each mol­ecule. The F atoms of one of the trifluoro­methyl groups are disordered over two sets of sites [in a 0.518 (14):0.482 (14) ratio], as are the F atoms of the tetra­fluoroborate anion [0.507 (14):0.493 (14) ratio]. The water mol­ecule is linked to one of the 2-trifluoro­methyl­benzimidazole mol­ecules  via  an N—H⋯O hydrogen bond.

2-Trifluoromethyl-1H-benzimidazol-3-ium tetrafluoroborate–2-trifluoromethyl-1H-benzimidazole–water (1/1/1)