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The title compound, [Tb(C 9 H 3 O 6 )(C 4 H 9 NO) 2 ], shows a rare-earth three-dimensional metal-organic framework structure. In this complex of an eight-coordinated Tb 3+  ion, the asymmetric unit contains one benzene-1,3,5-tricarb­oxy­lic ligand and two coordinated dimethyl­acetamide mol­ecules. Each Tb 3+  ion is coordinated by six O atoms from four carboxyl­ate groups of the benzene-1,3,5-tricarb­oxy­lic ligands and two O atoms from two terminal dimethyl­acetamide mol­ecules.

Poly[(μ4-benzene-1,3,5-tricarboxylato)bis(N,N-dimethylacetamide)terbium(III)]

Poly[(μ₄-benzene-1,3,5-tricarboxylato)bis(N,N-dimethylacetamide)terbium(III)]