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The asymmetric unit of the title compound, [MnCl 2 (C 16 H 20 N 2 O) 4 ]·2C 16 H 20 N 2 O, is composed of two coordinating  N -(adamantan-1-yl)pyridine-4-carboxamide mol­ecules, one Cl −  anion, an Mn II  ion, lying on an inversion centre, and one free  N -(adamantan-1-yl)pyridine-4-carboxamide mol­ecule. The distorted octa­hedral Mn environment comprises two terminal Cl atoms and four monodentate N atoms from four organic ligands. All the carbamoyl N atoms are involved in inter­molecular N—H⋯O hydrogen-bonding inter­actions which link the mol­ecules into a chain along the  a  axis.

trans-Tetrakis[N-(adamantan-1-yl)pyridine-4-carboxamide]dichloridomanganese(II)–N-(adamantan-1-yl)pyridine-4-carboxamide (1/2)