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In the title compound, [Ni(C(7)H(4)N(3)O(2))(2)(C(12)H(8)N(2))(2)]·CH(3)OH, the Ni(II) atom is six-coordinated in a distorted N(6) octa-hedral geometry and is chelated by two phenanthroline ligands and two phenyl-cyanamide groups which occupy cis positions. The (4-nitro-phen-yl)cyanamide anions act as monodentate ligands. There is one classical inter-molecular O-H⋯N hydrogen bond and several C-H⋯O hydrogen bonds are also observed.

cis-Bis[(4-nitrophenyl)cyanamido-κN1]bis(1,10-phenanthroline-κ2N,N′)nickel(II) methanol monosolvate

cis-Bis[(4-nitrophenyl)cyanamido-κN¹]bis(1,10-phenanthroline-κ²N,N′)nickel(II) methanol monosolvate