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In the title one-dimensional coordination polymer, {[ZnCl 2 (C 18 H 14 N 4 )]·0.25H 2 O}  n  , the Zn II  atom is coordinated by two chloride ions and two 4,4′-bis­(1 H -imidazol-1-yl)biphenyl ligands, generating a distorted tetra­hedral ZnCl 2 N 2  geometry. The dihedral angle between the benzene rings of the ligand is 51.0 (1)° and the dihedral angles between the benzene rings and their attached imidazole rings are 18.7 (2) and 45.9 (1)°. The bridging ligand leads to [10-1] polymeric chains in the crystal and the disordered water mol­ecule (occupancy 0.25) forms O—H⋯Cl hydrogen bonds.

acta crystallographica. section e

catena-Poly[[(dichloridozinc)-μ-4,4′-bis(1H-imidazol-1-yl)biphenyl-κ2N3:N3′] 0.25-hydrate]