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The mononuclear Ni II  amide, [Ni(C 12 H 21 N 2 Si) 2 ], has the Ni II  atom  N , N ′-chelated by the  N -silylated anilinide ligands. The ligands are arranged  cis  to each other and obey the  C   2 -symmetry operation. The two ends of the N—Si—N chelating unit exhibit different affinities for the metal atom: the Ni—N anilinide  bond length is 1.913 (3) Å and Ni—N amine  is 2.187 (3) Å. The four-coordinate Ni II  ion demonstrates a distorted tetra­hedral geometry.

Bis{N-[(diethylamino)dimethylsilyl]anilinido-κ2N,N′}nickel(II)

Bis{N-[(diethylamino)dimethylsilyl]anilinido-κ²N,N′}nickel(II)