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The asymmetric unit of the title complex, (C 9 H 15 N 2 ) 2 [Ni(C 4 N 2 S 2 ) 2 ], comprises one 4-dimethyl­amino-1-ethyl­pyri­din­ium cation and one half of a [Ni(mnt) 2 ] 2−  (mnt 2−  = maleo­nitrile­dithiol­ate) anion; the complete anion is generated by the application of a centre of inversion. The Ni II  ion is coordinated by four S atoms of two mnt 2−  ligands and exhibits a square-planar coordination geometry.

Bis(4-dimethylamino-1-ethylpyridinium) bis(1,2-dicyanoethene-1,2-dithiolato-κ2S,S′)nickelate(II)

Bis(4-dimethylamino-1-ethylpyridinium) bis(1,2-dicyanoethene-1,2-dithiolato-κ²S,S′)nickelate(II)