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The title compound, [Rh(C 5 H 7 O 2 )(C 30 H 21 P)(CO)]·0.5C 3 H 6 O, has two different complex molecules in the asymmetric unit, with the Rh I  atoms in slightly distorted square-planar coordination environments. The molecules are packed as two monomeric mol­ecules with one acetone solvent mol­ecule sitting at the centre.

(Acetylacetonato-κ2O,O′)carbonyl[tris(naphthalen-1-yl)phosphane-κP]rhodium(I) acetone hemisolvate

(Acetylacetonato-κ²O,O′)carbonyl[tris(naphthalen-1-yl)phosphane-κP]rhodium(I) acetone hemisolvate