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The Sm(III) ion in the title compound, [SmCl(3)(C(12)H(10)N(2)O)(3)], shows a coordination number of nine with a slightly distorted tricapped trigonal prismatic geometry based on a Cl(3)N(6) donor set. The mol-ecular structure is stabilized by three intra-molecular O-H⋯Cl hydrogen bonds.

Trichloridotris{N-[phenyl(pyridin-2-yl)methylidene]hydroxylamine-κ2N,N′}samarium(III)

Trichloridotris{N-[phenyl(pyridin-2-yl)methylidene]hydroxylamine-κ²N,N′}samarium(III)