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The title compound, [Fe 2 (C 14 H 10 NS 2 ) 2 (CO) 6 ], was synthesized as a structural and biochemical model for the active site of [FeFe]-hydrogenase. The bond lengths (Fe—Fe, Fe—S and Fe—C) and angles (C—Fe—Fe and Fe—S—Fe) are within expected ranges. The S⋯S distance [2.9069 (12) Å] and the dihedral angle between two Fe—S—Fe planes [78.5 (3)°] of the butterfly-shaped Fe 2 S 2  core are enlarged compared with related bridged dithiol­ate diiron analogues. The calculated 4-benzothia­zolebenzyl best planes are almost parallel [dihedral angle = 3.7 (7)°].

Bis{μ-[4-(1,3-benzothiazol-2-yl)phenyl]methanethiolato-κ4S,S′:S,S′}bis[tricarbonyliron(I)](Fe—Fe)

Bis{μ-[4-(1,3-benzothiazol-2-yl)phenyl]methanethiolato-κ⁴S,S′:S,S′}bis[tricarbonyliron(I)](Fe—Fe)