English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Plus monthly

Global: Zendy Tools annual

Global: Zendy Tools monthly

Global: Zendy Free Plan

The octa-hedral cluster core of the anion in the structure of the title compound, (C(16)H(36)N)(3)[Mo(6)(C(4)H(9)S)(6)(μ(3)-Cl)(7)(μ(3)-S)]·2H(2)O, has -3 site symmetry. Two μ(3)-Cl atoms fully occupy positions in the cluster core, while the remaining six positions are statistically occupied by Cl and S atoms in a 1:5 ratio. The fully occupied Cl-atom positions are located on sites with 3 symmetry, and the N atom of tetra-butyl-ammonium cation is located on a site with 2 symmetry. The structure contains also two disordered solvent water mol-ecules, one of which is located on a threefold rotation axis and the other in a general position, both with an occupancy of 0.25. The water mol-ecules are localized in cavities formed by the tetra-butyl-ammonium cations and the tert-butane-thiol-ate groups. The metal clusters are stacked in a cubic close packing arrangement along [001].

Tris(tetrabutylammonium) hexakis(tert-butanethiolato-κS)hepta-μ3-chlorido-μ3-sulfido-hexamolybdate dihydrate

Tris(tetrabutylammonium) hexakis(tert-butanethiolato-κS)hepta-μ₃-chlorido-μ₃-sulfido-hexamolybdate dihydrate