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In the hydrated title complex, [Mn(C 8 H 6 N 3 O 2 )(CH 3 CO 2 )(C 12 H 8 N 2 )(H 2 O) 2 ]·2H 2 O, the Mn II  atom is coordinated by two N atoms from a 1,10-phenanthroline ligand, two water O atoms, a monodentate acetate anion and an  O -monodentate 2-(1 H -benzotriazol-1-yl)acetate ligand, resulting in a distorted  cis -MnN 2 O 4  octa­hedral coordination geometry. The water O atoms are in a  trans  arrangement and one of them forms an intra­molecular O—H⋯O hydrogen bond to the uncoordinated O atom of the acetate ion. In the crystal, the complex mol­ecules and water mol­ecules are connected by O—H⋯O and O—H⋯N hydrogen bonds to generate a three-dimensional network.

acta crystallographica. section e

(Acetato-κO)diaqua[2-(1H-benzotriazol-1-yl)acetato-κO](1,10-phenanthroline-κ2N,N′)manganese(II) dihydrate