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Each mol­ecule of the title compound, C 12 H 18 N 4 O 6 , is located on an inversion centre at the mid-point of the central N—N bond. The azo groups C=N of the Schiff base group have an  E  conformation and the azo groups in the oxime C=N—O groups have a  Z  conformation. O–H⋯O hydrogen bonds link neighbouring mol­ecules into infinite monolayers perpendicular to the  a  axis.

Diethyl 2,2′-bis(hydroxyimino)-3,3′-(hydrazinediylidene)dibutanoate