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The asymmetric unit of the title compound, [Zn(C(4)H(8)NOS(2))(2)(C(18)H(12)N(6))]·1.5C(4)H(8)O(2), comprises a Zn-containing mol-ecule and one and a half dioxane mol-ecules as one of the solvent mol-ecules is located about a crystallographic inversion centre. The approximately square-pyramidal N(3)S(2) donor set is defined by two monodentate dithio-carbamate ligands and two pyridine and one triazine N atom from the tridentate triazine ligand. Mol-ecules are connected into a supra-molecular array via O-H⋯S and O-H⋯N hydrogen bonds. These stack along the b axis and the solvent mol-ecules reside in the channels thus formed.

acta crystallographica. section e

Bis[N-(2-hydroxyethyl)-N-methyldithiocarbamato-κS][2,4,6-tris(pyridin-2-yl)-1,3,5-triazine-κ3N1,N2,N6]zinc dioxane sesquisolvate