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In the title compound, [Hg(C 42 H 38 N 4 O 2 )](PF 6 ) 2 ·2CH 3 CN, the Hg II  cation lies on a twofold axis which is also the inter­nal symmetry element of the complete cationic complex. The Hg II  cation is coordinated by two symmetry-related C(carbene) atoms [Hg—C = 2.058 (9) Å] in a nearly linear geometry, with a C—Hg—C angle of 175.8 (5)°. There are weak inter­molecular C—H⋯F inter­actions in the crystal packing between an F atom of a hexa­fluoridophosphate anion and a –CH 2 – group of the bis-N-heterocyclic carbene ligand.

acta crystallographica. section e

{3,3′-Bis[(anthracen-9-yl)methyl]-1,1′-[(ethane-1,2-diyldioxy)bis(ethane-1,2-diyl)]bis(imidazol-2-ylidene)}mercury(II) bis(hexafluoridophosphate) acetonitrile disolvate