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The title compound, [RuCl(C 6 H 7 N) 2 (C 27 H 35 N 3 )]PF 6 ·C 3 H 6 O, was obtained unintentionally as the product of the reaction of 1,1′-methyl­enebis(4-methyl­pyridinium) hexa­fluoriso­phos­phate and RuCl 3 (tpy*) (tpy* is 4,4′,4′′-tri- tert -butyl-2,2′:6′,2′′-terpyridine) in the presence of triethyl­amine and LiCl. The mol­ecular structure of the complex displays an octa­hedral geometry around the Ru II  ion and the unit cell contains an acetone solvent mol­ecule and one orientationally disordered PF 6   −  anion (occupancy ratio 0.75:0.25) which is hydrogen bonded to two H atoms of the tpy* ligand of the nearest [RuCl(pic) 2 (tpy*)] +  cation (pic is 4-methyl­pyridine). One of the  tert -butyl groups of the tpy* ligand is also disordered over two sets of sites in a 0.75:0.25 ratio.

acta crystallographica. section e

trans-Chloridobis(4-methylpyridine-κN)(4,4′,4′′-tri-tert-butyl-2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)ruthenium(II) hexafluoridophosphate acetone monosolvate