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The title compound, [ZnCl(2)(C(21)H(15)N(3))], was obtained from the reaction of ZnCl(2)·4H(2)O with 4'-phenyl-terpyridine (L) and disodium 2,6-dipicolinate. The Zn(2+) cation is ligated by the N atoms of the tridentate L ligand and two chloride anions, forming a ZnN(3)Cl(2) polyhedron with a distorted trigonal-bipyramidal coordination geometry. In the crystal, nonclassical C-H⋯Cl hydrogen bonds are observed.

Dichlorido(4′-phenyl-2,2′:6′,2′′-terpyridyl)zinc