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The title complex, [Cu 3 WBrOS 3 (C 18 H 15 P) 3 ], a neutral heavily distorted cubane-like W/S/Cu cluster, was self-assembled from ammonium trithio­tungstate(VI), cuprous bromide and triphenyl­phosphane in  N , N -dimethyl­formamide. The average Cu—Br, Cu—S and W—μ 3 -S bond lengths are 2.731 (2), 2.318 (2) and 2.256 (2) Å, respectively, in the distorted cubane-like skeleton. The W atom exhibits tetra­hedral geometry, formed by one terminal O atom and three μ 3 -S atoms; the W—O bond length is 1.728 (6) Å. Each Cu atom is coordinated by one P atom from a triphenyl­phosphane ligand, and two μ 3 -S and one μ 3 -Br atoms, forming a distorted tetra­hedral coordination geometry.

μ3-Bromido-oxidotri-μ3-sulfido-tris(triphenylphosphane-κP)tricopper(I)tungsten(VI)

μ₃-Bromido-oxidotri-μ₃-sulfido-tris(triphenylphosphane-κP)tricopper(I)tungsten(VI)