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In the title coordination polymer, [Cd(C 16 H 12 O 8 S)(H 2 O) 2 ]  n  , the Cd II  ion is situated on a crystallographic twofold rotation axis, being coordinated by four O atoms from two bidentate 4,4′-[sulfonyl­bis­(1,4-phenyl­ene­oxy)]diacetate ( L ) ligands and two water mol­ecules in a highly distorted CdO 6  octa­hedral geometry. Each complete ligand  L , which is also generated by twofold symmetry with the S atom lying on the rotation axis, bridges two Cd II  atoms to form a polymeric zigzag chain propagating in the [10-1] direction. O—H⋯O hydrogen bonds between the coordinated water mol­ecules and carboxyl­ate O atoms are involved in the packing.

catena-Poly[(diaquacadmium)-μ-4,4′-[sulfonylbis(1,4-phenyleneoxy)]diacetato-κ4O,O′:O′′,O′′′]

catena-Poly[(diaquacadmium)-μ-4,4′-[sulfonylbis(1,4-phenyleneoxy)]diacetato-κ⁴O,O′:O′′,O′′′]