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The title compound, [Fe 2 (C 15 H 12 N 2 S 3 )(CO) 6 ], was prepared as an aza­dithiol­atodiiron model for the active site of [FeFe]-hydrogenase. The Fe 2 S 2  core adopts a butterfly shape, with each metal having a pseudo square-pyramidal geometry. The  N -substituted aza­dithiol­ate is μ 2 -κ 4   S , S ′: S , S ′-coordinated to the Fe(CO) 3  moieties to form two fused six-membered rings with different conformations. The sum of the C—N—C angles around the N atom [356.85 (15)°] indicates a flattening of the trigonal–pyramidal geometry about the N atom and an increase in the degree of  sp   2 -hybridization.

{μ-2-[4-(1,3-Benzothiazol-2-yl)phenyl]-2-azapropane-1,3-dithiolato-κ4S,S′:S,S′}bis[tricarbonyliron(I)]

{μ-2-[4-(1,3-Benzothiazol-2-yl)phenyl]-2-azapropane-1,3-dithiolato-κ⁴S,S′:S,S′}bis[tricarbonyliron(I)]