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In the title complex, [RhCl(C 44 H 32 OP 2 )]·CH 3 OH, the Rh I  ion is coordinated by a naphthyl group of a partially oxidized 2,2′-bis­(diphenyl­phosphan­yl)-1,1′-binaphthyl (BINAP) ligand in a η 4  mode, one P atom of the diphenyl­phosphanyl group and one Cl atom. The P=O group does not inter­act with the Rh I  ion but accepts an O—H⋯O hydrogen bond from the methanol solvent mol­ecule.

(+)-Chlorido[(1,2,3,4-η;κP2′)-2′-diphenylphosphanyl-2-diphenylphosphoryl-1,1′-binaphthyl]rhodium(I) methanol monosolvate

(+)-Chlorido[(1,2,3,4-η;κP^2′)-2′-diphenylphosphanyl-2-diphenylphosphoryl-1,1′-binaphthyl]rhodium(I) methanol monosolvate