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In the title coordination polymer, {[Cd 2 (C 10 H 9 O 5 ) 2 (C 10 H 8 N 2 ) 2 (C 3 H 7 NO) 2 (H 2 O) 2 ](NO 3 ) 2 }  n  , the 3-(4-carb­oxy­phen­oxy)propionate monoanion  O , O ′-chelates to a Cd II  cation through the aliphatic carboxyl­ate end. One of these O atoms is also connected to the metal cation from an inversion-related metal atom. The five O atoms bonded to the metal centre form a penta­gon, above and below which are located the N atoms of the 4,4′-bipyridine mol­ecules. The polycationic ribbon propagates along the  b  axis of the unit cell. The (aromatic) carboxyl end of the monoanion connects adjacent ribbons into a layer motif in the (102) plane. The nitrate ions are hydrogen bonded to the layer. The geometry of the Cd II  atom is a  trans -N 2 O 5 Cd penta­gonal bipyramid.

acta crystallographica. section e

catena-Poly[[[bis[μ-3-(4-carboxyphenoxy)propionato]-κ3O1,O1′:O1;κ3O1:O1,O1′-bis[aqua(N,N-dimethylformamide-κO)cadmium]]-μ-4,4′-bipyridine-κ2N:N′] dinitrate]