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In the title compound, C(20)H(22)N(4)O(6)S, the phenyl and benzene rings form a dihedral angle of 58.75 (5)°. Intra-molecular N-H⋯O and N-H⋯N hydrogen bonds generate two S(6) and one S(7) ring motif, respectively. In the crystal, mol-ecules are linked via N-H⋯O, N-H⋯N, C-H⋯S and C-H⋯O hydrogen bonds, forming two-dimensional networks parallel to the bc plane.

MethylN-({[2-(2-methoxyacetamido)-4-(phenylsulfanyl)phenyl]amino}[(methoxycarbonyl)imino]methyl)carbamate