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In the title compound, [Cd(C 10 H 6 NO 2 ) 2 ]  n  , the Cd II  atom is coordinated by three O atoms and two N atoms from four quinoline-3-carboxyl­ate ( L   − ) ligands, leading to a distorted trigonal–bipyramidal geometry. The  L   −  ligands link the Cd II  atoms into a plane parallel to (100), with one ligand being tridentate, coordinating  via  the N atom and chelating a second Cd atom, and the other being bidentate, bridging two Cd atoms  via  the N and one O atom.. This two-dimensional network extends into a double-layer network by π–π inter­actions, with centroid–centroid distances of 3.680 (2) and 3.752 (2) Å. Another type of π–π inter­action between pyridine rings [centroid–centroid distance = 3.527 (2) Å] leads to a three-dimensional supra­molecular architecture.

acta crystallographica. section e

Poly[(μ2-quinoline-3-carboxylato-κ2N:O)(μ2-quinoline-3-carboxylato-κ3N:O,O′)cadmium]