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The title compound, [Cu(NCS)(C 16 H 12 N 2 )]  n  , was synthesised under hydro­thermal conditions. The Cu I  ion shows distorted tetra­hedral geometry being coordinated by two N atoms from a 5-phenyl-2,2′-bipyridine ligand and by the N and S atoms from two different thio­cyanate anions. The Cu I  ions are bridged by thio­cyanide groups, forming a one-dimensional coordination polymer along the  b  axis. The crystal packing is through van der Waals contacts and C—H⋯π inter­actions.

catena-Poly[[(5-phenyl-2,2′-bipyridine-κ2N,N′)copper(I)]-μ-thiocyanido-κ2N:S]

catena-Poly[[(5-phenyl-2,2′-bipyridine-κ²N,N′)copper(I)]-μ-thiocyanido-κ²N:S]