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In the centrosymmetric dimeric title compound, [Cu 2 Cl 4 (C 16 H 20 N 2 O) 4 ]·0.5H 2 O, the Cu II  atom is in a distorted trigonal–bipyramidal environment defined by two bridging Cl atoms, one terminal Cl atom and two N atoms from two monodentate 4-(adamantan-1-ylcarbamo­yl)pyridine ligands. The amine N atoms are involved in intra­molecular N—H⋯O and inter­molecular N—H⋯Cl hydrogen bonds. The latter hydrogen bonds link the complex mol­ecules into a ribbon along [010]. The uncoordinated water mol­ecule is 0.25-occupied.

Di-μ-chlorido-bis{bis[4-(adamantan-1-ylcarbamoyl)pyridine-κN]chloridocopper(II)} hemihydrate