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The title compound, [Cr(C 28 H 32 OP 2 Si 2 )(CO) 4 ], was obtained by the ligand-exchange reaction of Cr(CO) 6  with (Ph 2 PSiMe 2 ) 2 O in refluxing toluene. The CrC 4 P 2  coordination geometry is distorted octa­hedral, with a P—Cr—P bite angle of 99.22 (4)°.

Tetracarbonyl[bis(diphenylphosphanyl)tetramethyldisiloxane-κ2P,P′]chromium(0)

Tetracarbonyl[bis(diphenylphosphanyl)tetramethyldisiloxane-κ²P,P′]chromium(0)