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The asymmetric unit of the title compound, [NiCl 2 (C 19 H 9 F 6 N 3 )], contains one half-mol­ecule residing on a crystallographic twofold rotation axis. The title compound crystallizes in space group  C 2/ c  while the previously reported polymorph was reported in  P 2 1 / c  [Baldovino-Pantaleón  et al.  (2006  ▶ ).  Adv. Synth. Catal.   348 , 236–242]. The Ni 2+  ion exhibits a penta­coordinate distorted trigonal–bipyramidal NiCl 2 N 3  geometry, with two Cl atoms in the equatorial plane. In the crystal, mol­ecules are linked by inter­molecular C—F⋯π [F⋯centroid = 2.9676 (14) Å] inter­actions.

A second monoclinic polymorph of {2,6-bis[(2,4,5-trifluorophenyl)iminomethyl]pyridine-κ3N,N′,N′′}dichloridonickel(II)

A second monoclinic polymorph of {2,6-bis[(2,4,5-trifluorophenyl)iminomethyl]pyridine-κ³N,N′,N′′}dichloridonickel(II)