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In the title coordination polymer, [Sn(CH 3 ) 3 (C 6 H 4 N 3 )]  n  , the Sn IV  atom is five-coordinated in a distorted trigonal–bipyramidal geometry with the methyl groups in equatorial positions and two N atoms of two symmetry-related benzotriazolide anions in axial positions. The anion bridges adjacent metal atoms, forming zigzag polymeric chains parallel to [011] and [0    1].

catena-Poly[[trimethyltin(IV)]-μ-1,2,3-benzotriazol-1-ido-κ2N1:N3]

catena-Poly[[trimethyltin(IV)]-μ-1,2,3-benzotriazol-1-ido-κ²N¹:N³]