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In the title compound, [Sm(C 48 H 45 N 10 O 3 )(H 2 O)]·CH 3 CN, the Sm III  ion is coordinated by the hepta­dentate tris­(2-{5-[(4-methyl­pheny)diazen­yl]-2-oxidobenzyl­idene­amino}­eth­yl)amine trianionic ligand and a water mol­ecule. The resulting SmN 4 O 4  coordination polyhedron is a distorted square anti­prism. In the crystal, complex mol­ecules are linked by O—H⋯O hydrogen bonds.

Aqua[tris(2-{5-[(4-methylphenyl)diazenyl]-2-oxidobenzylideneamino}ethyl)amine]samarium(III) acetonitrile monosolvate